You will find stainless steel somewhere in any swimming pool – even if it is only a few screws and nuts. Though they can be made of other materials these days, like plastic, stainless steel still has its domains:
From the wide-ranged family of stainless steels, with relationships that are very hard to understand for the average layman, two groups have proved to be very reliable for swimming pools accessories all over the world.
After deciding to have a certain material, and after receiving and mounting a beautiful, gleaming stainless steel ladder into his swimming pool, the pool owner will most certainly not be pleased to detect brown discolorations on the ladder or other parts after a rather short time. In this context, the term „stainless steel can’t rust“ is frequently used. This may suggest to the customer that either the material or the processing is faulty. Although manufacturing certainly cannot be avoided completely, they are still very, very rare. Even if your customer may not like it – in most cases, the water quality or external influences have caused the discoloration or corrosion. As we have already said above, even „stain“less steel consists mostly of iron and is not really non-corrosive but, to a certain extent, resistant to corrosion.
This resistance is caused by an oxide layer which is formed with the help of the chromium on the steel surface. This surface, called passive layer, protects thesteel permanently from corrosion. If this passive layer ist destroyed, the steel loses its resistance.
Even fully automatic chlorine proportioners do not function completely faultlessly, and should be subjected to regular maintenance.
Concrete pools are armed with steel mats. It happens so that during the installation of ladders or handrails, the rods get accidentally drilled into. The consequence is rust, which pours from the drillhole and settles on the screws.
It is appropriate to be skeptical if the swimming pool owner proudly tells the following: „Look at the water – it’s crystal clear, even though we have not changed the water in 12 years.“ Only that your ladder has been rusty since last year. And under the circumstances given, that’s no wonder: for the chloride concentration can only be decreased by adding fresh water. Otherwise, chlorides and many other water chemicals cannot leave the pool water. So, you can imagine what a cute little chemical cocktail the (now not quite so proud) pool owner has got in his water. The pool water should be changed completely at least once a year.
If the pool owner does not leave the water care up to the automatic chlorine proportioner but adds chlorine himself, he must take care not to put the chlorine tablet (or powder) directly onto the ladder step. Upon dissolution, there are chloride concentrations exceeding the tolerances by far.
If a stainless steel screw is fixed with a tool which, for example, fixed some plain steel screw before, minuscule particles of the plain steel screw can be transferred to the stainless steel screw, and lead to contact corrosion on the stainless steel screw head.
In modern piping, mainly plastic or corrosion proof materials are used. However, people did not consider them worth their while in the 60’s and early 70’s. Therefore, even when a pool is filled for the very first time through such pipes, rust particles can be transported into it. The rust searches and finds the cool stainless steel surface, settles there, and starts working soon, which means it destroys the passive layer.
Stainless steel parts are often welded together. It is important that the welding residues, like blue film, cinder, and tarnishing are removed from the steel surface. This is accomplished by pickling. Stainless steel etchants are available as liquids or pastes. The pickle removes a tiny part of the surface, and the contamination also. Of course, this also destroys the protective passive layer on the stainless steel, but this is able to reconstruct itself in a matter of hours without any assistance. If the pickling is not conducted efficiently, the remaining welding residues bloom in the aggressive pool water.
Incorrect cleaning is, besides the chlorides, the main reason for problems with stainless steel parts. The expert easily recognises the corrosion reasons rather easily. Instead of shining metal, a deep rust-red is the basic colour of the entire stainless steel surface. When asked, the pool owner often claims that only detergents permitted for swimming pools have been used. However, even highly acidiferous tile cleaning agents are permitted – which are absolutely not suitable for stainless steel.
As automatic chlorine proportioners do not measure the chloride value, the chlorine values are often equalled or confused with the chloride value.
There is a very simple and quick method to measure the chloride value, though. By using the chloride tablet counting method, the chloride value can be detemined within a few minutes, as precisely as 100 mg/l. Simply take a water sample and add tablets until the water colour changes from yellow to brown. Count the tablets added, subtract one, and multiply the remainder x 100.
Example:
The sample volume (10ml) changes its colour after 7 tablets. (7 – 1) x 100 = 600mg/l chloride content.